Abstract

The behavior of the electrons in a dense electron gas is analyzed quantum-mechanically by a series of canonical transformations. The usual Hamiltonian corresponding to a system of individual electrons with Coulomb interactions is first re-expressed in such a way that the long-range part of the Coulomb interactions between the electrons is described in terms of collective fields, representing organized "plasma" oscillation of the system as a whole. The Hamiltonian then describes these collective fields plus a set of individual electrons which interact with the collective fields and with one another via short-range screened Coulomb interactions. There is, in addition, a set of subsidiary conditions on the system wave function which relate the field and particle variables. The field-particle interaction is eliminated to a high degree of approximation by a further canonical transformation to a new representation in which the Hamiltonian describes independent collective fields, with ${n}^{\ensuremath{'}}$ degrees of freedom, plus the system of electrons interacting via screened Coulomb forces with a range of the order of the inter electronic distance. The new subsidiary conditions act only on the electronic wave functions; they strongly inhibit long wavelength electronic density fluctuations and act to reduce the number of individual electronic degrees of freedom by ${n}^{\ensuremath{'}}$. The general properties of this system are discussed, and the methods and results obtained are related to the classical density fluctuation approach and Tomonaga's one-dimensional treatment of the degenerate Fermi gas.

Keywords

PhysicsCoulombCanonical transformationElectronHamiltonian (control theory)Degenerate energy levelsQuantum mechanicsWave functionFermi gasDegrees of freedom (physics and chemistry)Electronic densityCondensed matter physicsQuantum electrodynamicsAtomic physicsQuantumDensity functional theory

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Publication Info

Year
1953
Type
article
Volume
92
Issue
3
Pages
609-625
Citations
1824
Access
Closed

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David Böhm, David Pines (1953). A Collective Description of Electron Interactions: III. Coulomb Interactions in a Degenerate Electron Gas. Physical Review , 92 (3) , 609-625. https://doi.org/10.1103/physrev.92.609

Identifiers

DOI
10.1103/physrev.92.609