Abstract

If you look for holes, you will find them in a novel 3D metal–organic framework complex with zeolite MTN topology. The framework of [{Cd(H2O)3}34(N4C6H12)17]Cl68⋅46 H2O⋅68 DMF greatly expands the original structure of MTN and contains large cages with a volume of about 2522 Å3 (see structure). MTN=zeolite socony mobil – thirty-nine, DMF=N,N-dimethylformamide. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2005/z462260_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

Keywords

ZeoliteTopology (electrical circuits)Volume (thermodynamics)MetalMetal-organic frameworkContent (measure theory)ChemistryNanotechnologyMaterials scienceOrganic chemistryPhysicsEngineeringCatalysisMathematicsThermodynamicsElectrical engineeringAdsorption

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Publication Info

Year
2005
Type
article
Volume
44
Issue
25
Pages
3845-3848
Citations
215
Access
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Cite This

Qianrong Fang, Guangshan Zhu, Ming Xue et al. (2005). A Metal–Organic Framework with the Zeolite MTN Topology Containing Large Cages of Volume 2.5 nm<sup>3</sup>. Angewandte Chemie International Edition , 44 (25) , 3845-3848. https://doi.org/10.1002/anie.200462260

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DOI
10.1002/anie.200462260