A Radical Anion Salt of 2,5‐Dimethyl‐N,N′‐dicyanoquinonediimine with Extremely High Electrical Conductivity

Abstract

Metallic conductivity that increases continuously up to 1.3 K and achieves values of over 500000 S cm−1 is exhibited by single crystals of the radical-anion salt depicted here, which was prepared by electrocrystallization. The multidimensional electronic conductivity is discussed on the basis of the crystal structure. The CuI ions are arranged in chains, each of which is surrounded by four stacks of dicyanoquinonediimine radical anions (one negative charge per "dimer").

Keywords

Salt (chemistry)IonElectrical resistivity and conductivityChemistryConductivityMaterials scienceInorganic chemistryOrganic chemistryPhysical chemistryPhysics

Affiliated Institutions

Related Publications

C–H.I− interactions in ferrocene derivatives: structures of (Ferrocenylmethyl)triphenylphosphonium iodide and 1,1'-ferrocenediylbis(methyltriphenylphosphonium iodide) dichloromethane solvate (1/1)

Christopher Glidewell , C.M. Zakaria , George Ferguson +1 more

The cations in (ferrocenylmethyl)triphenylphosphonium iodide, [{(C5H5)Fe(C5Ha)}CH2P(C6Hs)3]+.I -, (1), and in 1, l'-ferrocenediylbis(methyltriphenylphosphonium iodide) dichlo...

1994 Acta Crystallographica Section C Crys... 10 citations

Molecular Dynamics Simulation of the Ionic Liquid N-Ethyl-N,N-dimethyl-N-(2-methoxyethyl)ammonium Bis(trifluoromethanesulfonyl)imide

Leonardo J. A. Siqueira , Mauro C. C. Ribeiro

Thermodynamics, structure, and dynamics of an ionic liquid based on a quaternary ammonium salt with ether side chain, namely, N-ethyl-N,N-dimethyl-N-(2-methoxyethyl)ammonium bis...

2007 The Journal of Physical Chemistry B 71 citations

Structures of (ferrocenylmethyl)trimethylammonium iodide and hexa-N-methylferrocene-1,1'-diylbis(methylammonium iodide)

George Ferguson , John F. Gallagher , Christopher Glidewell +1 more

(Ferrocenylmethyl)trimethylammonium iodide (1), [C 14-\nH20FeN][I], Mr = 385.07, monoclinic, P2dc, a =\n8.6236 (5), b = 13.5926 (10), c = 12.8623 (6) A, ~ =\n102.792 (4)° , V = ...

1994 Acta Crystallographica Section B Stru... 23 citations

Apparent hydroxyl radical production by peroxynitrite: implications for endothelial injury from nitric oxide and superoxide.

Joseph S. Beckman , ThomasJ Beckman , Jake Y. Chen +2 more

Superoxide dismutase reduces injury in many disease processes, implicating superoxide anion radical (O2-.) as a toxic species in vivo. A critical target of superoxide may be nit...

1990 Proceedings of the National Academy o... 7029 citations

Pyrrolidinium Imides: A New Family of Molten Salts and Conductive Plastic Crystal Phases

Douglas R. MacFarlane , P. Meakin , Junyong Sun +2 more

A new family of molten salts is reported, based on the N-alkyl, N-alkyl pyrrolidinium cation and the bis(trifluoromethane sulfonyl)imide anion. Some of the members of the family...

1999 The Journal of Physical Chemistry B 1065 citations

Publication Info

Year: 1986
Type: article
Volume: 25
Issue: 8
Pages: 740-741
Citations: 424
Access: Closed

External Links

View on DOI.org

Social Impact

Altmetric

A Radical Anion Salt of 2,5‐Dimethyl‐N,N′‐dicyanoquinonediimine with Extremely High Electrical Conductivity

PlumX Metrics

Social media, news, blog, policy document mentions

Citation Metrics

424

OpenAlex

Cite This

APA Style

                            
                                
                                    Alexander Aumüller, 
                                
                                    Peter Erk, 
                                
                                    G. Klebe
                                
                                et al.
                            
                            (1986). 
                            A Radical Anion Salt of 2,5‐Dimethyl‐<i>N,N</i>′‐dicyanoquinonediimine with Extremely High Electrical Conductivity. 
                            Angewandte Chemie International Edition in English
                            , 25
                            (8)
                            , 740-741.
                            https://doi.org/10.1002/anie.198607401
                        

Identifiers

DOI: 10.1002/anie.198607401

A Radical Anion Salt of 2,5‐Dimethyl‐<i>N,N</i>′‐dicyanoquinonediimine with Extremely High Electrical Conductivity