Abstract
The access of guest species to the binding sites of adsorbent determines the metal‐binding capacity of materials, which is important for example in environmental remediation efforts. It is shown that MP‐HMS, the mercaptopropylsilane‐functionalized derivative of the molecualr sieve HMS, with its regular pore structure is a much better Hg 2⊕ absorbent than silica gels, in which functionalization leads to pore blocking (see Figure). magnified image
Keywords
Affiliated Institutions
Related Publications
Recent Progress in the Synthesis of Porous Carbon Materials
Abstract In this review, the progress made in the last ten years concerning the synthesis of porous carbon materials is summarized. Porous carbon materials with various pore siz...
Adsorption Study of Surface and Structural Properties of MCM-41 Materials of Different Pore Sizes
Nitrogen adsorption measurements were performed over a wide range of relative pressures (10-6−0.995) for a series of siliceous MCM-41 samples obtained using alkyltrimethylammoni...
Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores
Use of amphiphilic triblock copolymers to direct the organization of polymerizing silica species has resulted in the preparation of well-ordered hexagonal mesoporous silica stru...
New vistas in zeolite and molecular sieve catalysis
Zeolites and zeolite-like molecular sieves are able to \nrecognize, discriminate, and organize molecules with \nprecisions that can be less than 1 Å. Because these struc...
Tailored Porous Materials
Tailoring of porous materials involves not only chemical synthetic techniques for tailoring microscopic properties such as pore size, pore shape, pore connectivity, and pore sur...
Publication Info
- Year
- 1997
- Type
- article
- Volume
- 9
- Issue
- 6
- Pages
- 500-503
- Citations
- 701
- Access
- Closed
External Links
Social Impact
Social media, news, blog, policy document mentions
Citation Metrics
Cite This
Identifiers
- DOI
- 10.1002/adma.19970090611