Abstract
Recent studies show that the SEI on lithium and on anodes in liquid nonaqueous solutions consists of many different materials including , LiF, LiCl, , alkoxides, and nonconducting polymers. The equivalent circuit for such a mosaic‐type SEI electrode is extremely complex. It is shown that near room temperature the grain‐boundary resistance (Rgb) for polyparticle solid electrolytes is larger than the bulk ionic resistance. Up to now, all models of SEI electrodes ignored the contribution of Rgb to the overall SEI resistance. We show here that this neglect has no justification. On the basis of recent results, we propose here for SEI electrodes equivalent circuits which take into account the contribution of grain‐boundary and other interfacial impedance terms. This model accounts for a variety of different types of Nyquist plots reported for lithium and electrodes in liquid nonaqueous and polymer electrolytes.
Keywords
ElectrolyteElectrodeMaterials scienceNyquist plotPolymerLithium (medication)Grain boundaryElectrical impedanceEquivalent circuitFast ion conductorAnodeComposite materialChemical engineeringChemistryElectrochemistryElectrical engineeringVoltageDielectric spectroscopy
Affiliated Institutions
Related Publications
Review on modeling of the anode solid electrolyte interphase (SEI) for lithium-ion batteries
A passivation layer called the solid electrolyte interphase (SEI) is formed on electrode surfaces from decomposition products of electrolytes. The SEI allows Li+ transport and b...
SEI Layer Formation on Amorphous Si Thin Electrode during Precycling
The morphological and compositional changes of the solid electrolyte interphase (SEI) layer formed on the surface of Si thin electrodes during precycling were investigated. At t...
A High Capacity Calcium Primary Cell Based on the Ca–S System
Abstract Conversion reaction cells afford the ability to explore new energy storage paradigms that transcend the dogma of small, low‐charge cations essential to intercalative pr...
All‐Solid Lithium Electrodes with Mixed‐Conductor Matrix
The concept of a novel all‐solid composite electrode is presented. One example of such a composite contains a finely dispersed reactant, , in a solid mixed‐conducting matrix, . ...
Factors Which Limit the Cycle Life of Rechargeable Lithium (Metal) Batteries
Failure mechanisms due to high charging rates of rechargeable lithium batteries comprised of Li metal anodes, cathodes (tunneled structure), and electrolyte solutions based on t...
Publication Info
- Year
- 1997
- Type
- article
- Volume
- 144
- Issue
- 8
- Pages
- L208-L210
- Citations
- 1087
- Access
- Closed
External Links
Social Impact
Altmetric
PlumX Metrics
Social media, news, blog, policy document mentions
Citation Metrics
1087
OpenAlex
Cite This
E. Peled,
Diana Golodnitsky,
G. Ardel
(1997).
Advanced Model for Solid Electrolyte Interphase Electrodes in Liquid and Polymer Electrolytes.
Journal of The Electrochemical Society
, 144
(8)
, L208-L210.
https://doi.org/10.1149/1.1837858
Identifiers
- DOI
- 10.1149/1.1837858