Abstract

Nonemissive tetraphenylethene (TPE) 1 and its diphenylated derivative 2 were induced to emit intensely by aggregate formation. Crystalline aggregates of the dyes emitted bluer lights than their amorphous counterparts. The emissions of the TPE dyes could be switched off and on continuously and reversibly by wetting and dewetting with solvent vapors, respectively, manifesting their ability to optically sense volatile organic compounds. The light-emitting diodes fabricated from 1 and 2 were turned on at ∼2.9 and ∼5V and emitted blue lights with maximum luminance of ∼1800 and ∼11000cd∕m2, respectively.

Keywords

OLEDOptoelectronicsDewettingMaterials scienceDiodeAmorphous solidWettingDerivative (finance)PhotochemistryChemistryThin filmNanotechnologyOrganic chemistryLayer (electronics)

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Publication Info

Year
2007
Type
article
Volume
91
Issue
1
Citations
517
Access
Closed

Citation Metrics

517
OpenAlex
1
Influential
501
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Cite This

Yongqiang Dong, Jacky W. Y. Lam, Anjun Qin et al. (2007). Aggregation-induced emissions of tetraphenylethene derivatives and their utilities as chemical vapor sensors and in organic light-emitting diodes. Applied Physics Letters , 91 (1) . https://doi.org/10.1063/1.2753723

Identifiers

DOI
10.1063/1.2753723

Data Quality

Data completeness: 77%