Abstract
The following complexes of copper(II) and 4,6,4',6'-tetramethyl-2,2'-bipyridine (tmb) have been prepared: CuX2tmb, where X = NO3,Cl,Br, and ½SO4; Cu(tmb)2X2, nH2O, where X = NO3 (n = 1) and ClO4, (n = 0, 1, and 2); and Cu(tmb)2X(ClO4), nH2O, where X = NO3 (lz = 1) and Cl (n = 0). The magnetic moments of the compounds range from 1.89 to 2.05 B.M. The results of conductivity, molecular weight, and spectral measurements suggest the occurrence of four-, five-, and six-coordinate copper(II).
Keywords
CopperChemistrySupramolecular chemistryCoordination complexQuantum chemistryBiocatalysis22'-BipyridineBipyridineCrystallographyMacromoleculeCrystal structureInorganic chemistryMedicinal chemistryPhysical chemistryIonic liquidCatalysisOrganic chemistryMetal
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Publication Info
- Year
- 1965
- Type
- article
- Volume
- 18
- Issue
- 9
- Pages
- 1331-1338
- Citations
- 12
- Access
- Closed
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J. R. Hall,
MR Litzow,
RA Plowman
(1965).
Coordination compounds of substituted 1,10-Phenanthrolines and related dipyridyls. VI. Complexes of copper(II) and 4,6,4',6'-Tetramethyl-2,2'-bipyridine.
Australian Journal of Chemistry
, 18
(9)
, 1331-1338.
https://doi.org/10.1071/ch9651331
Identifiers
- DOI
- 10.1071/ch9651331