Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes

Abstract

In the presence of moderately strong acids in CH3CN, cobalt complexes with BF2-bridged diglyoxime ligands are active catalysts for the reduction of protons to H2 at potentials as positive as -0.28 V vs. SCE.

Keywords

CobaltCatalysisChemistryHydrogenElectrocatalystCombinatorial chemistryInorganic chemistryElectrochemistryBiochemistryOrganic chemistryPhysical chemistryElectrode

Affiliated Institutions

California Institute of Technology US

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Publication Info

Year: 2005
Type: article
Issue: 37
Pages: 4723-4723
Citations: 278
Access: Closed

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APA Style

                            
                                    Xile Hu, 
                                
                                    Brandi M. Cossairt, 
                                
                                    Bruce S. Brunschwig
                                
                                et al.
                            
                            (2005). 
                            Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes. 
                            Chemical Communications
                            
                            (37)
                            , 4723-4723.
                            https://doi.org/10.1039/b509188h

Identifiers

DOI: 10.1039/b509188h