Abstract
(R)- and (S)- enantiomers of alkyl aryl sulfoxides can be obtained by chromatographic resolution of the racemic mixtures of the sulfoxides on a microporous homochiral Zn-organic polymer or by simultaneous catalytic oxidation of the corresponding sulfides with H2O2 and enantioselective chromatographic resolution of the resulting sulfoxides in a one-pot process.
Keywords
ChemistryEnantioselective synthesisMicroporous materialEnantiomerAlkylArylOrganic chemistrySulfoxideResolution (logic)CatalysisChromatography
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Publication Info
- Year
- 2007
- Type
- article
- Volume
- 129
- Issue
- 43
- Pages
- 12958-12959
- Citations
- 254
- Access
- Closed
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Cite This
Alexey L. Nuzhdin,
Danil N. Dybtsev,
Konstantin P. Bryliakov
et al.
(2007).
Enantioselective Chromatographic Resolution and One-Pot Synthesis of Enantiomerically Pure Sulfoxides over a Homochiral Zn−Organic Framework.
Journal of the American Chemical Society
, 129
(43)
, 12958-12959.
https://doi.org/10.1021/ja076276p
Identifiers
- DOI
- 10.1021/ja076276p