Abstract

A new approach for the synthesis of extremely large PAHs in high yield is the oxidative cyclodehydrogenation of suitable oligophenylenes under Kovacic conditions. The synthesis of oligophenylene precursors and their cyclodehydrogenation (figure) are presented, and the supramolecular structures observed for large PAHs are discussed.

Keywords

Yield (engineering)Supramolecular chemistryChemistryAromaticityPolycyclic aromatic hydrocarbonOrganic chemistryMaterials scienceMolecule

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Publication Info

Year
1998
Type
article
Volume
4
Issue
11
Pages
2099-2109
Citations
236
Access
Closed

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Markus Müller, Christian Kübel, Kläus Müllen (1998). Giant Polycyclic Aromatic Hydrocarbons. Chemistry - A European Journal , 4 (11) , 2099-2109. https://doi.org/10.1002/(sici)1521-3765(19981102)4:11<2099::aid-chem2099>3.0.co;2-t

Identifiers

DOI
10.1002/(sici)1521-3765(19981102)4:11<2099::aid-chem2099>3.0.co;2-t

Data Quality

Data completeness: 77%