Abstract

Mesoscopic solar cells, based on solution-processed organic-inorganic perovskite absorbers, are a promising avenue for converting solar to electrical energy. We used solution-processed organic-inorganic lead halide perovskite absorbers, in conjunction with organic hole conductors, to form high voltage solar cells. There is a dire need for low-cost cells of this type, to drive electrochemical reactions or as the high photon energy cell in a system with spectral splitting. These perovskite materials, although spin-coated from solution, form highly crystalline materials. Their simple synthesis, along with high chemical versatility, allows tuning their electronic and optical properties. By judicious selection of the perovskite lead halide-based absorber, matching organic hole conductor, and contacts, a cell with a ∼ 1.3 V open circuit voltage was made. While further study is needed, this achievement provides a general guideline for additional improvement of cell performance.

Keywords

Perovskite (structure)HalideMaterials scienceSolar cellOpen-circuit voltagePerovskite solar cellOptoelectronicsOrganic solar cellEnergy conversion efficiencyMesoscopic physicsPhotovoltaic systemNanotechnologyVoltageInorganic chemistryChemistryPolymerOrganic chemistryElectrical engineering

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Publication Info

Year
2013
Type
article
Volume
4
Issue
6
Pages
897-902
Citations
531
Access
Closed

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Eran Edri, Saar Kirmayer, David Cahen et al. (2013). High Open-Circuit Voltage Solar Cells Based on Organic–Inorganic Lead Bromide Perovskite. The Journal of Physical Chemistry Letters , 4 (6) , 897-902. https://doi.org/10.1021/jz400348q

Identifiers

DOI
10.1021/jz400348q