Abstract

A simple synthetic route for the preparation of high-quality CdSe/ZnSe core/shell nanocrystals without the use of any pyrophoric organometallic precursors is presented. Effective surface passivation of monodisperse CdSe nanocrystals is achieved by overcoating them with a ZnSe shell, applying zinc stearate as a zinc source. The resulting core/shell nanocrystals exhibit high room temperature photoluminescence efficiencies (60−85%) in organic solvents as well as in water after functionalization with mercaptoundecanoic acid (MUA).

Keywords

NanocrystalPhotoluminescencePassivationMaterials scienceZincShell (structure)DispersityLuminescenceChemical engineeringSurface modificationNanoparticleNanotechnologyZinc sulfideZinc stearateInorganic chemistryChemistryLayer (electronics)OptoelectronicsMetallurgyOrganic chemistryComposite materialPolymer chemistry

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Publication Info

Year
2002
Type
article
Volume
2
Issue
7
Pages
781-784
Citations
840
Access
Closed

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840
OpenAlex
16
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784
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Cite This

Peter Reiß, J. Bleuse, Adam Proń (2002). Highly Luminescent CdSe/ZnSe Core/Shell Nanocrystals of Low Size Dispersion. Nano Letters , 2 (7) , 781-784. https://doi.org/10.1021/nl025596y

Identifiers

DOI
10.1021/nl025596y

Data Quality

Data completeness: 77%