H2, N2, CO, and CO2 Sorption Properties of a Series of Robust Sodalite-Type Microporous Coordination Polymers

Abstract

H2, N2, CO, and CO2 are readily incorporated in the porous, 3D sodalitic frameworks of coordination polymers of the [ML2]n type, with M = Pd(II) or Cu(II) and HL = 2-hydroxypyrimidine or 4-hydroxypyrimidine. The metal ion and ligand functionalization modulate their sorption properties, making these materials suitable for gas storage and separation purposes.

Keywords

SorptionSodaliteChemistryMicroporous materialLigand (biochemistry)Coordination polymerPolymerMetal-organic frameworkInorganic chemistryPolymer chemistryZeoliteOrganic chemistryAdsorptionCatalysis

Affiliated Institutions

Universidad de Granada ES

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Publication Info

Year: 2006
Type: article
Volume: 45
Issue: 6
Pages: 2397-2399
Citations: 169
Access: Closed

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APA Style

                            
                                
                                    Jorge A. R. Navarro, 
                                
                                    E. Barea, 
                                
                                    Juan M. Salas
                                
                                et al.
                            
                            (2006). 
                            H<sub>2</sub>, N<sub>2</sub>, CO, and CO<sub>2</sub> Sorption Properties of a Series of Robust Sodalite-Type Microporous Coordination Polymers. 
                            Inorganic Chemistry
                            , 45
                            (6)
                            , 2397-2399.
                            https://doi.org/10.1021/ic060049r
                        

Identifiers

DOI: 10.1021/ic060049r