Abstract
The new hybrid inorganic-organic polymer In(2)(OH)(3)[O(4)C(8)H(4)](1.5) has been hydrothermally obtained. Conditions for the synthesis are reported. The crystal structure of this material has been established by single-crystal X-ray diffraction: it is monoclinic, with space group P2(1)/c (Nomicron. 14), a = 6.772(1) A, b = 10.329(2) A, c = 20.152(3) A, beta = 97.573(3) degrees. The In atoms are octahedrally coordinated by three hydroxide groups and three different molecules of carboxylate ligand. The resulting polymeric 3D structure can be envisaged as having been generated from a honeycomb (6,3) 2D that is cross-linked by the BDC organic anions. Data of IR and TGA-DTA studies, as well as the results of reduction of nitroaromatics and selective oxidation of organic sulfide reactions catalyzed by the new material, are reported.
Keywords
ChemistryMonoclinic crystal systemSupramolecular chemistryCarboxylateCrystallographyCrystal structureMoleculeHydroxideCatalysisLigand (biochemistry)SulfideInorganic chemistrySingle crystalStereochemistryOrganic chemistry
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Publication Info
- Year
- 2002
- Type
- article
- Volume
- 41
- Issue
- 9
- Pages
- 2429-2432
- Citations
- 225
- Access
- Closed
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Cite This
Berta Gómez‐Lor,
Enrique Gutiérrez‐Puebla,
M. Iglesias
et al.
(2002).
In<sub>2</sub>(OH)<sub>3</sub>(BDC)<sub>1.5</sub> (BDC = 1,4-Benzendicarboxylate): An In(III) Supramolecular 3D Framework with Catalytic Activity.
Inorganic Chemistry
, 41
(9)
, 2429-2432.
https://doi.org/10.1021/ic0111482
Identifiers
- DOI
- 10.1021/ic0111482