Abstract

The synthesis and single crystal X-ray structures are reported of two interwoven cationic frameworks that are based upon tetrahedral and trigonal CuI ions; the resulting architectures are diamondoid, [CuI(bipy)2(PF6)]∞(bipy = 4,4′-bipyridyl)1, and honeycomb, [CuI)2(pz)3(SiF6)]∞(pz = pyrazine)2, respectively.

Keywords

DiamondoidPyrazineDenticityCationic polymerizationCrystallographyChemistryTetrahedronIonCoordination polymerTrigonal crystal systemCrystal structureStereochemistryPolymer chemistryMoleculeOrganic chemistry

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Publication Info

Year
1994
Type
article
Issue
11
Pages
1325-1325
Citations
356
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Leonard R. MacGillivray, S. Subramanian, Michael J. Zaworotko (1994). Interwoven two- and three-dimensional coordination polymers through self-assembly of Cu I cations with linear bidentate ligands. Journal of the Chemical Society Chemical Communications (11) , 1325-1325. https://doi.org/10.1039/c39940001325

Identifiers

DOI
10.1039/c39940001325