Abstract

The efficiency of photoelectrolysis with solar radiation can be greatly enhanced by using simultaneously illuminated n- and p-type electrodes. An energy level scheme for heterotype and homotype p-n photoelectrolysis cells is presented which explains the enhanced efficiency. Data are presented for the homotype n-GaP/p-GaP and the heterotype n-TiO2/p-GaP systems which support the energy model. H2 and O2 are produced in the n-TiO2/p-GaP cell without the need of an external anodic bias.

Keywords

PhotoelectrolysisOptoelectronicsBand gapAnodeMaterials scienceElectrodeChemistryElectrolysisPhysical chemistry

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Publication Info

Year
1976
Type
article
Volume
29
Issue
3
Pages
150-153
Citations
324
Access
Closed

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Arthur J. Nozik (1976). <i>p</i>-<i>n</i> photoelectrolysis cells. Applied Physics Letters , 29 (3) , 150-153. https://doi.org/10.1063/1.89004

Identifiers

DOI
10.1063/1.89004