Mechanical and Structural Consequences of PLA/PBAT Contamination in Polypropylene and Polystyrene Recycling

Abstract

The increasing use of biodegradable plastics derived from renewable sources (PLA, PHB, PBAT, and others) in the packaging industry raises controversies and risks related to potentially integrating these plastics into municipal waste streams, which may significantly hinder future recycling efforts. This publication addresses this issue by investigating a selected bio-based and biodegradable commercial mixture of poly(lactic acid) and poly(butylene adipate terephthalate) (PLA/PBAT), referred to as (BIO), in blends with polypropylene (PP) and polystyrene (PS). The blends were prepared with three different mass contents of 1, 5, and 10 wt.% using (PP) and (PS) as base materials. The effects of introducing biodegradable and bio-based plastics into municipal waste streams (PCR—Post-Consumer Recycling), which typically contain polypropylene, various grades of polyethylene, and polystyrene, remain unknown. The purpose of the study was to assess the consequences of contaminating municipal waste destined for recycling (using PP and PS as examples) with small amounts (between 1 and 10%) of BIO plastics. The designed experiment and the obtained results simulate the expected presence of BIO contamination in future PP and PS recyclates. The prepared mixtures were subjected to injection molding to produce test specimens, which were then analyzed for changes in their physical properties such as tensile strength, impact strength and hardness. Thermal properties were assessed using Differential Scanning Calorimetry (DSC), while dynamic properties were analyzed at variable temperatures using Dynamic Mechanical Thermal Analysis (DMTA). The tests provided insights into how the addition of selected, but insignificant ratios (of 1 to 10%) of biopolymers affects the properties of (PP) and (PS) compared to materials without content of biopolymers. The conducted tests of mechanical properties (static and dynamic) and thermomechanical properties have shown that the change in the properties of the mixture depends not only on the amount of biodegradable polymer but also on the nature of the load. It would be advisable to analyze mechanical properties in relation to the duration of the load; therefore, a long-term load analysis is necessary. For dynamic tests, a decrease in impact strength was demonstrated with increasing biodegradable polymer content in the produced mixtures. Similar behavior was recorded for hardness measurements. The results underscore the need for continued research, given the valuable findings for processors and the advancement of mechanical recycling technologies.

Affiliated Institutions

• Poznań University of Technology PL
• Częstochowa University of Technology PL

Related Publications