Abstract

More than 95% (in volume) of all of today's chemical products are manufactured through catalytic processes, making research into more efficient catalytic materials a thrilling and very dynamic research field. In this regard, metal-organic frameworks (MOFs) offer great opportunities for the rational design of new catalytic solids, as highlighted by the unprecedented number of publications appearing over the past decade. In this review, the recent advances in the application of MOFs in heterogeneous catalysis are discussed. MOFs with intrinsic thermocatalytic activity, as hosts for the incorporation of metal nanoparticles, as precursors for the manufacture of composite catalysts and those active in photo- and electrocatalytic processes are critically reviewed. The review is wrapped up with our personal view on future research directions.

Keywords

CatalysisNanotechnologyChemistryMetal-organic frameworkRational designHeterogeneous catalysisBiochemical engineeringOrganic chemistryMaterials scienceEngineering

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Publication Info

Year
2020
Type
review
Volume
120
Issue
16
Pages
8468-8535
Citations
1599
Access
Closed

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Cite This

Anastasiya Bavykina, Nikita Kolobov, Il Son Khan et al. (2020). Metal–Organic Frameworks in Heterogeneous Catalysis: Recent Progress, New Trends, and Future Perspectives. Chemical Reviews , 120 (16) , 8468-8535. https://doi.org/10.1021/acs.chemrev.9b00685

Identifiers

DOI
10.1021/acs.chemrev.9b00685
PMID
32223183

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Data completeness: 81%