Molecules isoelectronic with 2,2,2-triphenylethanol: multiple hydrogen-bonding modes in the structures of O-tritylhydroxylamine, Ph3CONH2, and triphenylmethanesulfenamide, Ph3CSNH2

1994 Acta Crystallographica Section C Crystal Structure Communications 3 citations

Abstract

O-Tritylhydroxylamine, C 19 H 17 NO (IV), forms dimers in the solid state which are made up from two different molecules; these dimers exhibit three type of hydrogen bond, intermolecular N-H...N and N-H...π(arene), and intramolecular (aryl)C-H...O. Triphenylmethanesulfenamide, C 19 H 17 NS (V), forms centrosymmetric dimers in the solid state in which N-H...S hydrogen bonds are the sole type observed

Keywords

Intramolecular forceHydrogen bondMoleculeIntermolecular forceChemistrySolid-stateCrystallographyHydrogenArylStereochemistryPhysical chemistryOrganic chemistry

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Publication Info

Year
1994
Type
article
Volume
50
Issue
8
Pages
1362-1366
Citations
3
Access
Closed

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C. Glidewell, G. Ferguson (1994). Molecules isoelectronic with 2,2,2-triphenylethanol: multiple hydrogen-bonding modes in the structures of O-tritylhydroxylamine, Ph3CONH2, and triphenylmethanesulfenamide, Ph3CSNH2. Acta Crystallographica Section C Crystal Structure Communications , 50 (8) , 1362-1366. https://doi.org/10.1107/s0108270194004439

Identifiers

DOI
10.1107/s0108270194004439