Abstract
Surface electronic states associated with defects produced by Ar-ion bombardment of Ti${\mathrm{O}}_{2}$ crystals have been studied by ultraviolet-photoemission, electron-energy-loss, and Auger spectroscopy and low-energy-electron diffraction. Evidence is given for three distinct phases dependent upon the extrinsic surface-defect concentration. Phase I contains isolated surface states 0.7 eV below the conduction band, phase II is associated with the creation of ${\mathrm{Ti}}^{3+}$ pairs, and phase III consists of a surface layer of ordered ${\mathrm{Ti}}_{2}$${\mathrm{O}}_{3}$.
Keywords
Materials sciencePhase (matter)Surface (topology)Auger electron spectroscopyEnergy (signal processing)Photoemission spectroscopyCrystallographySpectroscopySurface layerUltravioletAtomic physicsAnalytical Chemistry (journal)PhysicsLayer (electronics)X-ray photoelectron spectroscopyNuclear magnetic resonanceChemistryNanotechnologyNuclear physics
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Publication Info
- Year
- 1976
- Type
- article
- Volume
- 36
- Issue
- 22
- Pages
- 1335-1339
- Citations
- 500
- Access
- Closed
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Cite This
Victor E. Henrich,
G. Dresselhaus,
H. J. Zeiger
(1976).
Observation of Two-Dimensional Phases Associated with Defect States on the Surface of Ti<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>.
Physical Review Letters
, 36
(22)
, 1335-1339.
https://doi.org/10.1103/physrevlett.36.1335
Identifiers
- DOI
- 10.1103/physrevlett.36.1335