Abstract

We report broadband visible photoluminescence from solid graphene oxide, and modifications of the emission spectrum by progressive chemical reduction. The data suggest a gapping of the two-dimensional electronic system by removal of π-electrons. We discuss possible gapping mechanisms, and propose that a Kekule pattern of bond distortions may account for the observed behavior.

Keywords

PhotoluminescenceGrapheneOxideMaterials scienceBand gapElectronModulation (music)OptoelectronicsBroadbandNanotechnologyPhysicsOpticsQuantum mechanicsMetallurgy

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Year
2009
Type
article
Volume
94
Issue
11
Citations
561
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Closed

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Cite This

Zhengtang Luo, Patrick M. Vora, E. J. Melé et al. (2009). Photoluminescence and band gap modulation in graphene oxide. Applied Physics Letters , 94 (11) . https://doi.org/10.1063/1.3098358

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DOI
10.1063/1.3098358