Polysulfone/ZnO Modified Nanocomposite Films for the Removal of Dyes

Abstract

Wastewater can be reused in industrial processes, for domestic activities, and for agriculture. This is a strategy to address the global water shortage. Consequently, there is an ongoing search for new materials that can effectively remove contaminants from wastewater, as dyes are considered persistent pollutants. This study synthesized films based on polysulfone with chemically modified ZnO nanoparticles by the sonochemical method for application as an adsorbent material for indigo and crystal violet. The films were characterized by Fourier Transform Infrared Spectroscopy (FT-IR), X-Ray Diffraction (XRD), Thermogranimetric analysis (TGA), and Scanning Electron Microscopy (SEM); changes were observed with the incorporation of the nanoparticles. The results reveal that the films achieved a dye removal of 80 mg/g. The crystallite size was measured using the Scherrer equation for the polysulfone (PSF) sample, which was 0.024 nm, and using the same method the result obtained was 0.048 nm for the PSFZNO2 sample. The modification with L-serine is novel, as it is an amino acid and a non-toxic substance for the human body. There are few studies on this type of reagent regarding the modification of nanoparticles to provide them with different functionalities. This work was carried out in accordance with the principles of green chemistry, specifically using ultrasound technology, which promotes principles 6 and 9 by reducing energy consumption through the use of lower temperatures and short reaction times. Principles 2 and 3 are also addressed by modifying the surface of the nanoparticles directly. This process eliminates the need for intermediate steps or the use of highly toxic reagents.

Affiliated Institutions

• Secretaría de Ciencia, Humanidades, Tecnología e Innovación MX
• Universidad Autónoma de Coahuila MX
• Universidad Juárez del Estado de Durango MX

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