Abstract
Abstract Recent developments in the study of the intercalation of organoammonium ions into layered silicates are reviewed. The new developments of the applications of the organoammonium-exchanged layered silicates include the selective adsorption of toxic compounds from water, the immobilization of photo and electroactive species to construct novel photo and electrofunctional materials, and the complexation with organic polymers for the enhancement of the mechanical properties. The conversion of the layered solids to three dimensional nanoporous solids with novel microstructures and adsorptive properties has also been successfully done. The novel controlled properties achieved by the modification with the adsorption of organoammonium ions open new opportunities to tailor the properties of the inorganic-organic nanostructured materials.
Keywords
Affiliated Institutions
Related Publications
Polymer Layered Silicate Nanocomposites
Abstract Polymer nanocomposites with layered silicates as the inorganic phase (reinforcement) are discussed. The materials design and synthesis rely on the ability of layered si...
[Co5(im)10⋅2 MB]∞: A Metal-Organic Open-Framework with Zeolite-Like Topology
A highly robust metal-organic zeotype was created by expansion of the zeolite topology. The novel nanoporous material [Co5(im)10⋅2 MB]∞ (see structure) exhibits not only a zeoli...
Molecular dynamics simulations of organically modified layered silicates
Molecular dynamics (MD) simulations are used to study the static and dynamic properties of 2:1 layered silicates ion exchanged with alkyl-ammonium surfactants. These systems are...
25th Anniversary Article: MXenes: A New Family of Two‐Dimensional Materials
Recently a new, large family of two‐dimensional (2D) early transition metal carbides and carbonitrides, called MXenes, was discovered. MXenes are produced by selective etching o...
Transition Metal Dichalcogenides and Their Intercalates
Abstract The transition metal dichalcogenides form a group of layered, highly anisotropic compounds which exhibit interesting and unusual physical properties. Compounds formed f...
Publication Info
- Year
- 1997
- Type
- article
- Volume
- 70
- Issue
- 11
- Pages
- 2593-2618
- Citations
- 432
- Access
- Closed
External Links
Social Impact
Social media, news, blog, policy document mentions
Citation Metrics
Cite This
Identifiers
- DOI
- 10.1246/bcsj.70.2593