Abstract

We have succeeded in fabricating the mostly crystallized Si:H materials having a wide optical band gap of up to 2.4 eV by means of a reactive sputtering technique with a low substrate temperature of \ensuremath{\sim}100 K. The structural analysis showed that the materials consist of small crystalline silicon particles surrounded by hydrogen atoms, whose diameters are 20--30 A\r{}. The widening of the optical band gap can be explained by a three-dimensional quantum-well effect in the small particles.

Keywords

Materials scienceMicrocrystallineBand gapSputteringSubstrate (aquarium)SiliconHydrogenMicrocrystalline siliconPotential wellQuantum dotOptoelectronicsCondensed matter physicsCrystalline siliconThin filmNanotechnologyCrystallographyPhysicsChemistry

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Year
1988
Type
article
Volume
38
Issue
8
Pages
5726-5729
Citations
451
Access
Closed

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Shoji Furukawa, Tatsuro Miyasato (1988). Quantum size effects on the optical band gap of microcrystalline Si:H. Physical review. B, Condensed matter , 38 (8) , 5726-5729. https://doi.org/10.1103/physrevb.38.5726

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DOI
10.1103/physrevb.38.5726