Abstract

We report strong variations in the Raman spectra for different single-layer graphene samples obtained by micromechanical cleavage. This reveals the presence of excess charges, even in the absence of intentional doping. Doping concentrations up to ∼1013cm−2 are estimated from the G peak shift and width and the variation of both position and relative intensity of the second order 2D peak. Asymmetric G peaks indicate charge inhomogeneity on a scale of less than 1μm.

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Year
2007
Type
article
Volume
91
Issue
23
Citations
843
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Closed

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C. Casiraghi, S. Pisana, K. S. Novoselov et al. (2007). Raman fingerprint of charged impurities in graphene. Applied Physics Letters , 91 (23) . https://doi.org/10.1063/1.2818692

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DOI
10.1063/1.2818692