Abstract

Freestanding single-crystal complete nanorings of zinc oxide were formed via a spontaneous self-coiling process during the growth of polar nanobelts. The nanoring appeared to be initiated by circular folding of a nanobelt, caused by long-range electrostatic interaction. Coaxial and uniradial loop-by-loop winding of the nanobelt formed a complete ring. Short-range chemical bonding among the loops resulted in a single-crystal structure. The self-coiling is likely to be driven by minimizing the energy contributed by polar charges, surface area, and elastic deformation. Zinc oxide nanorings formed by self-coiling of nanobelts may be useful for investigating polar surface–induced growth processes, fundamental physics phenomena, and nanoscale devices.

Keywords

NanoringPolarMaterials scienceNanotechnologyZincEpitaxyChemical physicsSingle crystalCrystallographyLayer (electronics)ChemistryPhysicsMetallurgy

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Publication Info

Year
2004
Type
article
Volume
303
Issue
5662
Pages
1348-1351
Citations
1434
Access
Closed

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1434
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5
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1355
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Cite This

Xiangyang Kong, Yong Ding, Rusen Yang et al. (2004). Single-Crystal Nanorings Formed by Epitaxial Self-Coiling of Polar Nanobelts. Science , 303 (5662) , 1348-1351. https://doi.org/10.1126/science.1092356

Identifiers

DOI
10.1126/science.1092356
PMID
14988559

Data Quality

Data completeness: 77%