Abstract
X-ray measurements in ErCl3 and ErI3 solutions indicate that there is a firmly held octahedral arrangement of H2O molecules around the Er3+ ion. In addition, there are present Er3+–Cl2— and Er3+–I2— ion-pair complexes. Finally there is a large amount of order introduced into the structure by the presence of the ions, with evidence for an ``icelike'' quasi-lattice.
Keywords
IonOctahedronIonic bondingMoleculeCrystallographyLattice (music)ChemistryCrystal structureMaterials sciencePhysicsOrganic chemistry
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Publication Info
- Year
- 1960
- Type
- article
- Volume
- 33
- Issue
- 4
- Pages
- 1079-1082
- Citations
- 70
- Access
- Closed
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Cite This
George W. Brady
(1960).
Structure in Ionic Solutions. IV.
The Journal of Chemical Physics
, 33
(4)
, 1079-1082.
https://doi.org/10.1063/1.1731337
Identifiers
- DOI
- 10.1063/1.1731337