Abstract
The probability function of Menke has been used as a basis for a statistical treatment of the intermolecular potentials in solutions of symmetrical molecules for which the entropy of mixing is the same as for an ideal solution of the same composition. The resulting expressions enable calculations to be made of the departure of iodine solutions from the ideal solution laws which agree satisfactorily with the observed departures.
Keywords
Ideal (ethics)Mixing (physics)Intermolecular forceIdeal solutionEntropy (arrow of time)Statistical physicsMathematicsBasis (linear algebra)ThermodynamicsMoleculePhysicsQuantum mechanicsLawGeometry
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Publication Info
- Year
- 1933
- Type
- article
- Volume
- 1
- Issue
- 12
- Pages
- 817-822
- Citations
- 164
- Access
- Closed
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Cite This
J. H. Hildebrand,
Scott E. Wood
(1933).
The Derivation of Equations for Regular Solutions.
The Journal of Chemical Physics
, 1
(12)
, 817-822.
https://doi.org/10.1063/1.1749250
Identifiers
- DOI
- 10.1063/1.1749250