Abstract
The absorption and fluorescence spectra of Nd3+ in NdCl3 diluted by LaCl3 have been examined with their Zeeman effect at 4.2° and less completely also at 77°K. The empirical energy-level diagram is complete up to 28 000 cm−1 except for the location of the 2K term. Crystal Stark splittings, magnetic properties, and intensities are compared to calculated values obtained from an intermediate coupling calculation of the 4f3 configuration.
Keywords
Zeeman effectIonAbsorption (acoustics)Spectral lineFluorescenceAtomic physicsAbsorption spectroscopyCoupling (piping)DiagramStark effectMaterials sciencePhysicsMagnetic fieldOpticsQuantum mechanicsMathematics
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Publication Info
- Year
- 1961
- Type
- article
- Volume
- 34
- Issue
- 5
- Pages
- 1602-1609
- Citations
- 125
- Access
- Closed
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Cite This
E. H. Carlson,
G. H. Dieke
(1961).
The State of the Nd3+ Ion as Derived from the Absorption and Fluorescence Spectra of NdCl3 and Their Zeeman Effects.
The Journal of Chemical Physics
, 34
(5)
, 1602-1609.
https://doi.org/10.1063/1.1701052
Identifiers
- DOI
- 10.1063/1.1701052