Abstract
The salts [MeEtim]2[MCl4]([MeEtim]+= 1-methyl-3-ethylimidazolium; M = Mn, Co, or Ni) are shown by EXAFS to dissolve in basic [MeEtim]Cl–AlCl3 ionic liquids to yield four-co-ordinate [MCl4]2–, and to dissolve in acidic [MeEtim]Cl–AlCl3 ionic liquids to yield six-co-ordinate [M(AlCl4)3]– anions.
Keywords
Ionic liquidYield (engineering)Extended X-ray absorption fine structureChemistryIonic bondingInorganic chemistryIonic compoundIonPhysical chemistryOrganic chemistryMaterials scienceAbsorption spectroscopyCatalysisOptics
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Publication Info
- Year
- 1990
- Type
- article
- Issue
- 4
- Pages
- 315-315
- Citations
- 68
- Access
- Closed
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Cite This
Andrew J. Dent,
Kenneth R. Seddon,
Tom Welton
(1990).
The structure of halogenometallate complexes dissolved in both basic and acidic room-temperature halogenoaluminate(III) ionic liquids, as determined by EXAFS.
Journal of the Chemical Society Chemical Communications
(4)
, 315-315.
https://doi.org/10.1039/c39900000315
Identifiers
- DOI
- 10.1039/c39900000315