Abstract

New approaches to synthesize photostable thiol-capped CdTe nanocrystals are reported. Post-preparative size-selective precipitation and selective photochemical etching have been developed as methods providing an increase of photoluminescence quantum efficiency of the nanocrystals of up to 40%. Some advantages of thiol-capping in comparison to conventional organometallic syntheses of quantum dots are discussed.

Keywords

NanocrystalCadmium telluride photovoltaicsQuantum dotThiolNanotechnologyMaterials sciencePhotoluminescenceEtching (microfabrication)ChemistryOptoelectronicsOrganic chemistry

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Publication Info

Year
2002
Type
article
Volume
106
Issue
29
Pages
7177-7185
Citations
1525
Access
Closed

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Nikolai Gaponik, Dmitri V. Talapin, Andrey L. Rogach et al. (2002). Thiol-Capping of CdTe Nanocrystals:  An Alternative to Organometallic Synthetic Routes. The Journal of Physical Chemistry B , 106 (29) , 7177-7185. https://doi.org/10.1021/jp025541k

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DOI
10.1021/jp025541k