Quantum and thermal effects in<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">H</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>dissociative adsorption: Evaluation of free energy barriers in multidimensional quantum systems
We have evaluated the sticking probability and activation energy for dissociation of ${\mathrm{H}}_{2}$ molecules on a Cu(110) surface by a reversible work formulation of quantu...