Charge Transfer on the Nanoscale: Current Status
This is the report of a DOE-sponsored workshop organized to discuss the status of our understanding of charge-transfer processes on the nanoscale and to identify research and ot...
Publications
11 shownElectron Transfer Reactions in Chemistry: Theory and Experiment (Nobel Lecture)
Abstract Since the late 1940s, the field of electron transfer processes has grown enormously, both in chemistry and biology. The development of the field, experimentally and the...
Chemical and Electrochemical Electron-Transfer Theory
One of the active areas in reaction kinetics during the post-war years has \nbeen that of electron-transfer reactions. These reactions constitute one type \nof oxidation...
ON THE THEORY OF OXIDATION—REDUCTION REACTIONS INVOLVING ELECTRON TRANSFER. V. COMPARISON AND PROPERTIES OF ELECTROCHEMICAL AND CHEMICAL RATE CONSTANTS<sup>1</sup>
Using a theory of electron transfers which takes cognizance of reorganization of the medium outside the inner coordination shell and of changes of bond lengths inside it, relati...
On the Theory of Chemiluminescent Electron-Transfer Reactions
A mechanism is described for chemiluminescent electron-transfer reactions. It is shown that in the case of very exothermic homogeneous electron-transfer reactions, the intersect...
The second R. A. Robinson Memorial Lecture. Electron, proton and related transfers
Past and current developments in electron and proton transfer and in related fields are described. Broad classes of reactions have been considered from a unified viewpoint which...
A new tunneling path for reactions such as H+H2→H2+H
The standard tunneling path in transition state theory for reactions such as H+H2→H2+H has been the so-called reaction path, namely the path of steepest ascent to the saddle poi...
On the Analytical Mechanics of Chemical Reactions. Quantum Mechanics of Linear Collisions
The analytical quantum mechanics of chemically reactive linear collisions is treated in the vibrationally near-adiabatic approximation. The ``reaction coordinate'' in this appro...
On the Theory of Electron-Transfer Reactions. VI. Unified Treatment for Homogeneous and Electrode Reactions
A unified theory of homogeneous and electrochemical electron-transfer rates is developed using statistical mechanics. The treatment is a generalization of earlier papers of this...
Theoretical relations among rate constants, barriers, and Broensted slopes of chemical reactions
A simple relation, ΔF* = (λ(1 + Δ/λ)^2)/4, derived originally for weak-overlap electron transfers, is explored in a slightly modified version for reactions with considerable res...
Frequent Co-Authors
Researcher Info
- h-index
- 11
- Publications
- 11
- Citations
- 12,977
- Institution
- Brookhaven National Laboratory
External Links
Identifiers
- ORCID
- 0000-0001-6547-1469
Impact Metrics
h-index
11
h-index: Number of publications with at least h citations each.