Abstract
Kinetic control of crystal growth in the presence of a coordinating ligand is critical for the formation of a new structure of elemental cobalt (ε-cobalt, the unit cell with the two different types of cobalt atoms is shown), which was discovered upon analyzing the metallic powder produced by the thermal decomposition of [Co2(CO)8] in solution in the presence of trioctylphosphane oxide [TOPO, Eq. (1)].
Keywords
CobaltThermal decompositionCrystal structureMetalPhase (matter)OxideDecompositionCrystallographyCrystal (programming language)Cobalt oxideMaterials scienceInorganic chemistryCrystal growthLigand (biochemistry)ChemistryChemical engineeringMetallurgyOrganic chemistryComputer science
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Publication Info
- Year
- 1999
- Type
- article
- Volume
- 38
- Issue
- 12
- Pages
- 1788-1791
- Citations
- 513
- Access
- Closed
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Cite This
Dmitry P. Dinega,
Moungi G. Bawendi
(1999).
A Solution-Phase Chemical Approach to a New Crystal Structure of Cobalt.
Angewandte Chemie International Edition
, 38
(12)
, 1788-1791.
https://doi.org/10.1002/(sici)1521-3773(19990614)38:12<1788::aid-anie1788>3.0.co;2-2
Identifiers
- DOI
- 10.1002/(sici)1521-3773(19990614)38:12<1788::aid-anie1788>3.0.co;2-2