Abstract

Relatively monodisperse, highly luminescent zinc blende ZnSe nanocrystals are synthesized in a hexadecylamine/trioctylphosphine coordination solvent. The controlled growth process affords tunable sample sizes. Pure band-edge fluorescence size-tunable between 2.8 and 3.4 eV is obtained at room temperature with quantum yields between 20% and 50% relative to Stilbene 420.

Keywords

Trioctylphosphine oxideLuminescenceNanocrystalDispersityMaterials scienceFluorescenceColloidSolventZincBand gapPhotochemistryBlueshiftPhotoluminescenceNanotechnologyOptoelectronicsChemical engineeringChemistryOpticsPhysical chemistryPolymer chemistryOrganic chemistry

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Publication Info

Year
1998
Type
article
Volume
102
Issue
19
Pages
3655-3657
Citations
549
Access
Closed

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Margaret A. Hines, Philippe Guyot‐Sionnest (1998). Bright UV-Blue Luminescent Colloidal ZnSe Nanocrystals. The Journal of Physical Chemistry B , 102 (19) , 3655-3657. https://doi.org/10.1021/jp9810217

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DOI
10.1021/jp9810217