Control over Interpenetration in Lanthanide−Organic Frameworks: Synthetic Strategy and Gas-Adsorption Properties

Abstract

Two isostructural lanthanide-organic frameworks (1 and 2) with 2-fold interpenetrating nets have been synthesized based on 1,4-benzenedicarboxylic acid (H(2)BDC). By application of an organic ligand with hindrance groups and a terminal chelating ligand to replace BDC and coordinated solvates, interpenetration has been effectively controlled. The gas-sorption properties of the noninterpenetrating net have been studied.

Keywords

IsostructuralLanthanideChemistrySorptionLigand (biochemistry)AdsorptionMetal-organic frameworkChelationInorganic chemistryPolymer chemistryChemical engineeringOrganic chemistryCrystal structureIon

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Publication Info

Year: 2010
Type: article
Volume: 49
Issue: 17
Pages: 7605-7607
Citations: 123
Access: Closed

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APA Style

                            
                                
                                    Haiyan He, 
                                
                                    Daqiang Yuan, 
                                
                                    Huiqing Ma
                                
                                et al.
                            
                            (2010). 
                            Control over Interpenetration in Lanthanide−Organic Frameworks: Synthetic Strategy and Gas-Adsorption Properties. 
                            Inorganic Chemistry
                            , 49
                            (17)
                            , 7605-7607.
                            https://doi.org/10.1021/ic100822s
                        

Identifiers

DOI: 10.1021/ic100822s

Control over Interpenetration in Lanthanide−Organic Frameworks: Synthetic Strategy and Gas-Adsorption Properties

Abstract

Keywords

Affiliated Institutions

Related Publications

Temperature and Concentration Control over Interpenetration in a Metal−Organic Material

Highly Porous and Stable Metal−Organic Frameworks: Structure Design and Sorption Properties

Microporous Metal−Organic Frameworks Formed in a Stepwise Manner from Luminescent Building Blocks

Effect of the guest solvent molecules on preparation of different morphologies of ZnO nanomaterials from the [Zn<sub>2</sub>(1,4-bdc)<sub>2</sub>(dabco)] metal-organic framework

H<sub>2</sub>, N<sub>2</sub>, CO, and CO<sub>2</sub> Sorption Properties of a Series of Robust Sodalite-Type Microporous Coordination Polymers

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