Abstract

The preparation and X-ray crystal structures of two coordination networks [Ag(BPCN)(CF3SO3)]·C6H61 and [Ag(BPCN)2]PF6 2 (BPCN = 4,4′-biphenyldicarbonitrile) are described; 1 consists of infinite chains; however, 2 exists as a ninefold interpenetrated diamondoid network.

Keywords

DiamondoidCounterionCrystallizationChemistryTopology (electrical circuits)CrystallographyIonStereochemistryOrganic chemistryMoleculeCombinatorics

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Publication Info

Year
1995
Type
article
Issue
21
Pages
2199-2200
Citations
82
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Closed

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Keith A. Hirsch, D. Venkataraman, Scott R. Wilson et al. (1995). Crystallization of 4,4′-biphenyldicarbonitrile with silver(<scp>I</scp>) salts: a change in topology concomitant with a change in counterion leading to a ninefold diamondoid network. Journal of the Chemical Society Chemical Communications (21) , 2199-2200. https://doi.org/10.1039/c39950002199

Identifiers

DOI
10.1039/c39950002199