Insulated Molecular Wires: Synthesis of Conjugated Polyrotaxanes by Suzuki Coupling in Water

Peter N. Taylor; Michael J. O’Connell; Luke A. McNeill; Michael J. Hall; Robin T. Aplin; Harry L. Anderson

doi:10.1002/1521-3773(20001002)39:19<3456::aid-anie3456>3.0.co;2-0

Abstract

Poly-para-phenylene polyrotaxane 1 is the first conjugated polyrotaxane. The naphthalene end groups prevent the β-cyclodextrin rings from slipping off the conjugated backbone in solution. The matrix-assisted laser desorption/ionization time-of-flight (MALDI-TOF) mass spectrum shows a series of oligomers, up to a [10]rotaxane.

Keywords

Conjugated systemRotaxaneMolecular wireSlippingPolymer chemistrySuzuki reactionChemistryCovalent bondCyclodextrinPhenyleneMaterials sciencePhotochemistryMoleculePolymerOrganic chemistrySupramolecular chemistryPalladium

Affiliated Institutions

University of Oxford GB

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Publication Info

Year: 2000
Type: article
Volume: 39
Issue: 19
Pages: 3456-3460
Citations: 255
Access: Closed

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APA Style

                            
                                
                                    Peter N. Taylor, 
                                
                                    Michael J. O’Connell, 
                                
                                    Luke A. McNeill
                                
                                et al.
                            
                            (2000). 
                            Insulated Molecular Wires: Synthesis of Conjugated Polyrotaxanes by Suzuki Coupling in Water. 
                            Angewandte Chemie International Edition
                            , 39
                            (19)
                            , 3456-3460.
                            https://doi.org/10.1002/1521-3773(20001002)39:19<3456::aid-anie3456>3.0.co;2-0
                        

Identifiers

DOI: 10.1002/1521-3773(20001002)39:19<3456::aid-anie3456>3.0.co;2-0

Data Quality

Data completeness: 77%