Abstract
Independent one-, two-, and even three-dimensional nets interpenetrate each other in many solid-state structures of polymeric, hydrogen-bonded nets and coordination polymers. For example, the interpenetration of the adamantane units of two diamondlike nets is shown on the right. A detailed and systematic examination of many interpenetrating nets of this kind is made, and implications for crystal engineering are discussed.
Keywords
Quantum entanglementAdamantanePolymerSolid-stateCrystal engineeringMaterials sciencePolymer scienceStatistical physicsHydrogen bondChemistryPhysicsMoleculeComposite materialQuantum mechanicsPhysical chemistryOrganic chemistry
Affiliated Institutions
Related Publications
Control over Interpenetration in Lanthanide−Organic Frameworks: Synthetic Strategy and Gas-Adsorption Properties
Two isostructural lanthanide-organic frameworks (1 and 2) with 2-fold interpenetrating nets have been synthesized based on 1,4-benzenedicarboxylic acid (H(2)BDC). By application...
Nanoporous, Interpenetrated Metal−Organic Diamondoid Networks
Reactions of Cd(NO(3))(2).4H(2)O with 4-cyanopyridine in the presence of ethanol or pyrazine guest molecules under hydro(solvo)thermal conditions afford two new cadmium coordina...
Interpenetrating diamondoid frameworks of silver(<scp>I</scp>) cations linked by N,N′-bidentate molecular rods
Three novel coordination polymers, [Ag(N–N)2]X (N–N = 4,4′-bipyridyl, X = CF3SO3––1; N–N = 4-cyanopyridine, X = BF4–, in two polymorphs, 2 and 3)], are prepared and investigated...
Interwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large Pores
Interpenetration (catenation) has long been considered a major impediment in the achievement of stable and porous crystalline structures. A strategy for the design of highly por...
Nonionic Triblock and Star Diblock Copolymer and Oligomeric Surfactant Syntheses of Highly Ordered, Hydrothermally Stable, Mesoporous Silica Structures
A family of highly ordered mesoporous (20−300 Å) silica structures have been synthesized by the use of commercially available nonionic alkyl poly(ethylene oxide) (PEO) oligomeri...
Publication Info
- Year
- 1998
- Type
- review
- Volume
- 37
- Issue
- 11
- Pages
- 1460-1494
- Citations
- 4314
- Access
- Closed
External Links
Social Impact
Altmetric
PlumX Metrics
Social media, news, blog, policy document mentions
Citation Metrics
4314
OpenAlex
Cite This
Stuart R. Batten,
Richard Robson
(1998).
Interpenetrating Nets: Ordered, Periodic Entanglement.
Angewandte Chemie International Edition
, 37
(11)
, 1460-1494.
https://doi.org/10.1002/(sici)1521-3773(19980619)37:11<1460::aid-anie1460>3.0.co;2-z
Identifiers
- DOI
- 10.1002/(sici)1521-3773(19980619)37:11<1460::aid-anie1460>3.0.co;2-z