Abstract
The authors studied the possibility of using a reducing intercalation compound such as MoO/sub 2/ or WO/sub 2/ as a replacement for metallic lithium in secondary electrochemical cells. In order to be of practical importance, a cell of this type requires good reversibility at both electrodes and a substantial potential difference between the two electrodes. Coupled with a highly oxidizing positive electrode such as LiCoO/sub 2/, they find that both WO/sub 2/ and MoO/sub 2/ are feasible substitutes for lithium negative electrodes. With improvements in cycling efficiency, materials such as these could improve the overall performance of secondary lithium intercalation cells.
Keywords
Lithium (medication)Intercalation (chemistry)ElectrodeOxidizing agentElectrochemistryMaterials scienceMetalElectrochemical cellInorganic chemistryChemistryMetallurgyPhysical chemistry
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Publication Info
- Year
- 1987
- Type
- article
- Volume
- 134
- Issue
- 3
- Pages
- 638-641
- Citations
- 194
- Access
- Closed
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Cite This
James J. Auborn,
Y. L. Barberio
(1987).
Lithium Intercalation Cells Without Metallic Lithium: and.
Journal of The Electrochemical Society
, 134
(3)
, 638-641.
https://doi.org/10.1149/1.2100521
Identifiers
- DOI
- 10.1149/1.2100521