Abstract
The purpose of this critical review is to give a representative and comprehensive overview of the arising developments in the field of magnetic metal-organic frameworks, in particular those containing cobalt(II). We examine the diversity of magnetic exchange interactions between nearest-neighbour moment carriers, covering from dimers to oligomers and discuss their implications in infinite chains, layers and networks, having a variety of topologies. We progress to the different forms of short-range magnetic ordering, giving rise to single-molecule-magnets and single-chain-magnets, to long-range ordering of two- and three-dimensional networks (323 references).
Keywords
MagnetOrganic moleculesVariety (cybernetics)Molecular magnetsRange (aeronautics)CobaltMagnetic fieldSingle chainNanotechnologyMagnetic momentChemical physicsCondensed matter physicsMaterials sciencePhysicsMoleculeMagnetizationComputer scienceQuantum mechanics
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Publication Info
- Year
- 2009
- Type
- review
- Volume
- 38
- Issue
- 5
- Pages
- 1353-1353
- Citations
- 2417
- Access
- Closed
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Cite This
Mohamedally Kurmoo
(2009).
Magnetic metal–organic frameworks.
Chemical Society Reviews
, 38
(5)
, 1353-1353.
https://doi.org/10.1039/b804757j
Identifiers
- DOI
- 10.1039/b804757j