Abstract
The combination of some three-atom bridges with paramagnetic 3d transition metal ions results in the systematic isolation of molecular magnetic materials, ranging from single-molecule and single-chain magnets to layered weak ferromagnets and three-dimensional porous magnets. The design strategy and role of secondary components, such as co-ligands, templates and other mixed short ligands are discussed.
Keywords
ParamagnetismMagnetFerromagnetismTemplateAtom (system on chip)MoleculeMaterials scienceTransition metalMolecular magnetsChain (unit)Chemical physicsCrystallographyIonMetalNanotechnologyChemistryCondensed matter physicsMagnetizationMagnetic fieldPhysicsOrganic chemistryCatalysisMetallurgy
Affiliated Institutions
Related Publications
Magnetic metal–organic frameworks
The purpose of this critical review is to give a representative and comprehensive overview of the arising developments in the field of magnetic metal-organic frameworks, in part...
Magnetic hysteresis up to 80 kelvin in a dysprosium metallocene single-molecule magnet
Breaking through the nitrogen ceiling Single-molecule magnets could prove useful in miniaturizing a wide variety of devices. However, their application has been severely hindere...
Metal–Organic Nanoporous Structures with Anisotropic Photoluminescence and Magnetic Properties and Their Use as Sensors
Shining bright: Porous metal–organic framework materials are important owing to their potential applications as sensors. A new family of nanoporous, multifunctional rare-earth m...
Interplay between the magnetic and transport properties in the III-V diluted magnetic semiconductor<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">Ga</mml:mi></mml:mrow><mml:mrow><mml:mn>1</mml:mn><mml:mi>−</mml:mi><mml:mi>x</mml:mi></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">Mn</mml:mi></mml:mrow><mml:mrow><mml:mi>x</mml:mi></mml:mrow></mml:msub></mml:mrow><mml:mi mathvariant="normal">As</mml:mi></mml:math>
Using a low-temperature molecular-beam epitaxy growth procedure, ${\mathrm{Ga}}_{1\ensuremath{-}x}{\mathrm{Mn}}_{x}\mathrm{As}$ --- a III-V diluted magnetic semiconductor --- is...
Revealing Noncovalent Interactions
Molecular structure does not easily identify the intricate noncovalent interactions that govern many areas of biology and chemistry, including design of new materials and drugs....
Publication Info
- Year
- 2007
- Type
- article
- Issue
- 3
- Pages
- 281-294
- Citations
- 501
- Access
- Closed
External Links
Social Impact
Altmetric
PlumX Metrics
Social media, news, blog, policy document mentions
Citation Metrics
501
OpenAlex
Cite This
Xin‐Yi Wang,
Zhe‐Ming Wang,
Song Gao
(2007).
Constructing magnetic molecular solids by employing three-atom ligands as bridges.
Chemical Communications
(3)
, 281-294.
https://doi.org/10.1039/b708122g
Identifiers
- DOI
- 10.1039/b708122g