Abstract
[reaction: see text] This paper describes the application of peroxide-based oxidants in the Pd(OAc)(2)-catalyzed acetoxylation and etherification of arene and alkane C-H bonds. Oxone in acetic acid and/or methanol proved particularly effective, and these transformations were applied to a wide variety of substrates.
Keywords
ChemistryMethanolAcetic acidAlkaneCatalysisPeroxideCombinatorial chemistryOrganic chemistryOxygenationHydrogen peroxideEnvironmentally friendly
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Publication Info
- Year
- 2006
- Type
- article
- Volume
- 8
- Issue
- 6
- Pages
- 1141-1144
- Citations
- 420
- Access
- Closed
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Cite This
Lopa V. Desai,
Hasnain A. Malik,
Melanie S. Sanford
(2006).
Oxone as an Inexpensive, Safe, and Environmentally Benign Oxidant for C−H Bond Oxygenation.
Organic Letters
, 8
(6)
, 1141-1144.
https://doi.org/10.1021/ol0530272
Identifiers
- DOI
- 10.1021/ol0530272