Abstract

We investigated the temperature dependence of the frequency of G peak in the Raman spectra of graphene on Si/SiO2 substrates. The micro-Raman spectroscopy was carried out under the 488 nm laser excitation over the temperature range from -190 to +100 degrees C. The extracted value of the temperature coefficient of G mode of graphene is chi = -0.016 cm-1/ degrees C for the single layer and chi = -0.015 cm-1/ degrees C for the bilayer. The obtained results shed light on the anharmonic properties of graphene.

Keywords

GrapheneRaman spectroscopyMaterials scienceAnharmonicityBilayer grapheneAtmospheric temperature rangeAnalytical Chemistry (journal)Spectral lineExcitationBilayerGraphene nanoribbonsCondensed matter physicsNanotechnologyChemistryOpticsPhysics

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Year
2007
Type
article
Volume
7
Issue
9
Pages
2645-2649
Citations
1197
Access
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Irene Calizo, Alexander A. Balandin, Wenzhong Bao et al. (2007). Temperature Dependence of the Raman Spectra of Graphene and Graphene Multilayers. Nano Letters , 7 (9) , 2645-2649. https://doi.org/10.1021/nl071033g

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DOI
10.1021/nl071033g