Abstract

Electroluminescence based on TADF, that is, thermally activated delayed fluorescence, is demonstrated in Sn4+–porphyrin complexes. On excitation by a short electrical pulse, prompt and delayed electroluminescence components were clearly observed. The delayed component was composed of both TADF and phosphorescence (see figure), and the TADF component significantly increased with increasing temperature.

Keywords

ElectroluminescencePhosphorescenceMaterials scienceFluorescencePorphyrinPhotochemistryOLEDDiodeExcitationOptoelectronicsLight-emitting diodeNanotechnologyOpticsChemistry

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Publication Info

Year
2009
Type
article
Volume
21
Issue
47
Pages
4802-4806
Citations
943
Access
Closed

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Cite This

Ayataka Endo, Mai Ogasawara, Atsushi Takahashi et al. (2009). Thermally Activated Delayed Fluorescence from Sn<sup>4+</sup>–Porphyrin Complexes and Their Application to Organic Light Emitting Diodes — A Novel Mechanism for Electroluminescence. Advanced Materials , 21 (47) , 4802-4806. https://doi.org/10.1002/adma.200900983

Identifiers

DOI
10.1002/adma.200900983