Abstract

An all-polymer semiconductor integrated device is demonstrated with a high-mobility conjugated polymer field-effect transistor (FET) driving a polymer light-emitting diode (LED) of similar size. The FET uses regioregular poly(hexylthiophene). Its performance approaches that of inorganic amorphous silicon FETs, with field-effect mobilities of 0.05 to 0.1 square centimeters per volt second and ON-OFF current ratios of >10 6 . The high mobility is attributed to the formation of extended polaron states as a result of local self-organization, in contrast to the variable-range hopping of self-localized polarons found in more disordered polymers. The FET-LED device represents a step toward all-polymer optoelectronic integrated circuits such as active-matrix polymer LED displays.

Keywords

Materials scienceOptoelectronicsPolymerPolaronTransistorDiodeAmorphous solidVariable-range hoppingField-effect transistorConjugated systemSemiconductorAmorphous siliconSiliconNanotechnologyElectrical engineeringThermal conductionVoltageChemistryCrystalline siliconPhysicsOrganic chemistryElectron

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Publication Info

Year
1998
Type
article
Volume
280
Issue
5370
Pages
1741-1744
Citations
2719
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Closed

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Henning Sirringhaus, Nir Tessler, Richard H. Friend (1998). Integrated Optoelectronic Devices Based on Conjugated Polymers. Science , 280 (5370) , 1741-1744. https://doi.org/10.1126/science.280.5370.1741

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DOI
10.1126/science.280.5370.1741